Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 5, Pages 614-615Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b211789d
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The complex trans-[Rh(Cl)(CO)(PPh3)(2)] (1) is an efficient catalyst precursor for the dehydrogenative borylation of alkenes without consumption of half the alkene substrate by hydrogenation, giving useful vinylboronate esters including 1,1-disubstituted derviatives that cannot be made by alkyne hydroboration.
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