Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 23, Pages 2916-2917Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b309185f
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Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1'-binaphthalenyl-2,2'-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The corresponding sec-alcohols can be obtained in high yields with good to excellent ee.
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