Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 20, Pages 2608-2609Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b308660g
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Monophosphanylation of the difluorostannane Is(2)SnF(2) ( Is = 2,4,6-triisopropylphenyl) with Si(PH2)(4) furnishes the first isolable fluoro( phosphanyl) stannane Is(2)Sn(F) PH2 1, which readily undergoes unique SiO2-assisted decompostion to [Is(2)Sn(PH)](2) 2 and HF, while further phosphanylation of 1 leads to the remarkably stable diphosphanylstannane Is(2)Sn(PH2)(2) 3; the latter reacts with Me3SnF at the glass-wall to give the first perstannylphosphonium pentafluorosilicate [P(SnMe3)(4)](+) SiF5- 4.
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