4.7 Article

Factors controlling the relative stabilities of cis- and trans-[PtX2L2] isomers: Chatt and Wilkins - 50 years on

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 2, Pages 278-279

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b210939e

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DFT computations reveal that cis-trans preferences in [PtX2(PR3)(2)] species are due to a combination of electrostatics, pi-backbonding, antisymbiosis, and solvation effects.

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