4.7 Article

A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 7, Pages 896-897

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b212823c

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The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.

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