4.7 Article

Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 6, Pages 696-697

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b212408d

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Catalytic hydrophosphination of propargyl alcohols by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)(2)(C5Me5) leads to the formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate.

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