☆ 4.7 Article

Halogen-induced selectivity in heterogeneous epoxidation is an electronic effect - fluorine, chlorine, bromine and iodine in the Ag-catalysed selective oxidation of ethene

CHEMICAL COMMUNICATIONS (2003)

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CHEMICAL COMMUNICATIONS
Volume -, Issue 10, Pages 1184-1185

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b302620e

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Categories

Chemistry, Multidisciplinary

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Selectivity promotion in the Ag-catalysed heterogeneous epoxidation of ethene correlates with halogen electron affinity showing that it is an electronic phenomenon rather than a steric or geometrical effect.

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