Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 12, Pages 1362-1363Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b300441d
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Dinuclear mu-oxo osmium porphyrins containing terminal Os=CPh2 bonds with a linear C=Os-O-Os=C moiety were prepared, which are reactive toward pyridine to form [Os(Por)(CPh2)(py)] and are active catalysts for inter- and intra-molecular cyclopropanation of alkenes and for carbene insertion into saturated C-H bonds.
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