Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 12, Pages 1438-1439Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b302579a
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The single crystal X-ray structure of the supramolecular complex formed between diphenyl-lambda(3)-iodane (Ph2IBF4) or 1-alkynyl(phenyl)-lambda(3)-iodane [(BuCCI)-C-t(Ph)BF4] and 1,10-phenanthroline indicates a hitherto unknown distorted trigonal bipyramidal geometry around iodine(III), in which 1,10-phenanthroline acts as a bidentate ligand and occupies equatorial sites.
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