Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 11, Pages 1248-1249Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b301806g
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{Fe(pmd)(2)[Cu(CN)(2)](2)} (pmd = pyrimidine) displays a rigid two-dimensional structure and undergoes thermal- and optical-driven spin crossover behaviour; cooperative elastic coupling between iron(II) ions in the framework induces thermal hysteresis in the HS <-> LS conversion and sigmoidal HS --> LS relaxation of the photo-induced HS state at low temperatures.
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