Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 5, Issue 17, Pages 3676-3683Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b302957n
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Spin crossover in halogenated ethyltetrazole complexes of Fe(II) was earlier explained(1) within the model of ordering arising from non-specific molecular interactions and is now analysed by using a quasi-chemical approximation taking into account specific interactions in HS-LS associates. Non-specific molecular interactions are also included employing the formalism of excess energies. The equations obtained predict both incomplete and two-step spin crossover and provide a rational explanation of these phenomena. A comparison is given of these two approaches to the description of critical phenomena in spin crossover.
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