Journal
SURFACE SCIENCE
Volume 522, Issue 1-3, Pages 34-46Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0039-6028(02)02248-3
Keywords
scanning tunneling microscopy; vibrations of adsorbed molecules; chemisorption; density functional calculations; copper
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We have exposed clean and oxygen-precovered Cu(110) surfaces to acetic acid to create adsorbed acetate. Our studies show the formation of a variety of ordered acetate structures depending on the initial oxygen exposure. We have observed the restructuring of step edges and the formation of ordered arrays of up-down steps. Using a purposeful coadsorption strategy, we have obtained images that assist us in developing models for the acetate structures. Fast Fourier transform infrared spectra have been obtained and Hartree-Fock calculations are included for comparison. (C) 2002 Published by Elsevier Science B.V.
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