Journal
DALTON TRANSACTIONS
Volume -, Issue 6, Pages 1041-1052Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b209103h
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A quarter of a century after its (serendipitous) discovery, the catalytic sequential chaining of two carbon monoxides into an organic substrate (the so called double carbonylation reaction), is still not well understood. After a review of the most important experimental results, this Perspective proposes a critical survey of the main organometallic models and outlines some rather neglected tracks. Finally, the issue of the chaining of more than two carbon monoxides is also addressed.
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