4.3 Article

A soluble block copolymer-supported bis-cinchona alkaloid ligand for the asymmetric dihydroxylation of olefins

Journal

SYNTHETIC COMMUNICATIONS
Volume 33, Issue 20, Pages 3545-3550

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1081/SCC-120024740

Keywords

polymer-supported ligand; asymmetric dihydroxylation; cinchona alkaloid; derivative; homogeneous catalysis

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A soluble block copolymer-supported ligand was prepared via polycondensation of a bis-cinchona alkaloid derivative, polyethylene glycol, and terephthaloyl chloride. Its application in the asymmetric dihydroxylation of olefins delivered very good enantioselectivity.

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