Journal
SYNTHETIC COMMUNICATIONS
Volume 33, Issue 5, Pages 827-831Publisher
MARCEL DEKKER INC
DOI: 10.1081/SCC-120016328
Keywords
water-soluble phosphine; aqueous phase catalysis; allylic isomerization
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A water-soluble rhodium bis-phosphine complex was used for the aqueous phase isomerization of three allylic alcohols. For the isomerization of cinnamyl alcohol, the-catalyst was recycled with slight loss of activity and the optimum phosphine:rhodium ratio was found to be 6:1.
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