4.1 Article Proceedings Paper

Catalytic reduction of molecular nitrogen in solutions

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 52, Issue 12, Pages 2555-2562

Publisher

SPRINGER
DOI: 10.1023/B:RUCB.0000019873.81002.60

Keywords

molecular nitrogen; reduction; reducing agents; protic media; FeMo cofactor

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Reports on nitrogen fixation in solution are reviewed. The optimum catalyst is the polynuclear complex. The reaction proceeds as a multielectron process, and the limiting step involves the electron transfer from a reducing agent.

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