The improvement in oxidation resistance of carbon by a graded SiC/SiO2 coating

A dense functionally gradient SiC/SiO2 coating has been developed to improve the oxidation resistance of carbon at elevated temperatures. SiC was coated on the surface of a graphite substrate by a reaction between thermally evaporated silicon and carbon at 1400 degreesC. The SiO2 layer was deposited by exposing the SiC coated specimens next to a bed of Si powder in a flowing H-2-H2O gas (P-H2O = 2.6 x 10(-2) atm) at 1400 degreesC. The formed SiC/SiO2 layers were dense and had gradient compositions with good adhesion to the carbon substrate. However, as the coating thickness increased, the coating layer became cracked and delaminated from the substrate due to thermal stress. The specimens with the continuous SiC/SiO2 layer showed a remarkably improved oxidation resistance up to 1200 degreesC. (C) 2003 Elsevier Ltd. All rights reserved.