Journal
ARKIVOC
Volume -, Issue -, Pages 185-192Publisher
ARKAT USA INC
DOI: 10.3998/ark.5550190.0004.b19
Keywords
alkaloids; hydrolulolidone; (+)-aspidospermidine
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The aspidosperma alkaloid precursor (-)-(4aR,8aS,8R)-4a-ethyl-decahydroquinolin-7-one 7 (hydrolilolidone) was prepared from (+)-(1'S,4aR, 8aS)- 4a-ethyl-1-(1'-phenylethyl)octahydroquinolin-7-one 3. In addition, a synthesis of (+)- aspidospermidine 9 using compound 7 as starting material is described.
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