Journal
AICHE JOURNAL
Volume 49, Issue 1, Pages 214-224Publisher
WILEY
DOI: 10.1002/aic.690490119
Keywords
-
Categories
Ask authors/readers for more resources
This kinetic analysis compares homogeneous and heterogeneous catalysts for the cyclization of 6-aminohex-1-yne. The reaction was studied as a model for the direct addition of amine N- H bonds to CC multiple bonds (hydroamination). Kinetic modeling showed that the metal-catalyzed hydroamination reaction is followed by a proton-catalyzed isomerization of the primary reaction product, 2-methylene-pipelidine, to the thermodynamically more stable 2-methyl-1,2-dehydropiperidine.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available