Journal
HELVETICA CHIMICA ACTA
Volume 86, Issue 8, Pages 2928-2936Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.200390241
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Amino-alcohol derivatives of fragrant, volatile aldehydes and ketones were synthesized in a one-pot procedure by sequential cyanohydrin formation with trimethylsilyl cyanide and reduction with lithium aluminium hydride, or by ammonolysis of epoxide precursors. The amino alcohols are nonvolatile, stable properfumes releasing fragrant carbonyls by oxidation with sodium periodate or sodium bismuthate. Examples include amino alcohol properfumes of citronellal, Lilial(R), lauryl aldehyde, menthone, benzaldehyde, and anisaldehyde.
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