4.2 Article

Charge-discharge mechanism of LiCoPO4 cathode for rechargeable lithium batteries

Journal

ELECTROCHEMISTRY
Volume 71, Issue 12, Pages 1136-1138

Publisher

ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.71.1136

Keywords

cathode; olivine; LiCoPO4

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The structure of ordered-olivine LiCoPO4 was identified by neutron diffraction measurements. A 4.8 V discharge profile was demonstrated using coin-type cells. XAFS and magnetic measurements indicated that the high-voltage plateau of Li1-xCoPO4 corresponds to the Co2+ /Co3+ redox reaction.

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