4.4 Article

Demulsification of emulsions exploited by enhanced oil recovery system

Journal

SEPARATION SCIENCE AND TECHNOLOGY
Volume 38, Issue 16, Pages 4079-4094

Publisher

MARCEL DEKKER INC
DOI: 10.1081/SS-120024720

Keywords

water-in-oil emulsion; demulsification; alkali; surfactant; polymer; microwave radiation

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Experimental data are presented to show the influence of the enhanced oil recovery system's components, alkali, surfactant, and polymer, on the demulsification and light transmittance of the water separated from the emulsions. Among which, the effects of surfactants, polyoxyethylene (10) alkylphenol ether (OP-10) and sodium petroleum sulfonate (CY-1) on emulsion stability, are the strongest of any component, the effects of polymer, hydrolytic polyacrylamide (HPAM) 3530S, on emulsion stability are the weakest. This research also suggests a possible emulsion minimization approach, which could be implemented in refineries utilizing microwave radiation. Compared with conventional heating, microwave radiation can effectively enhance the demulsification rate by an order of magnitude and increase the light transmittance of the water separated from the emulsions. The demulsification efficiency may reach 100% in a very short. time under microwave radiation.

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