Journal
CHIMIA
Volume 57, Issue 10, Pages 601-606Publisher
SWISS CHEMICAL SOC
DOI: 10.2533/000942903777678812
Keywords
biomimetic synthesis; Mukaiyama aldol reaction; porphobilinogen; silyl enol ether
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The synthesis of a pyrazol analogon of porphobilinogen is described. The Mukaiyama crossed aldol reaction is the key step of our approach. The retrosynthetic analysis follows the mechanism for the biosynthesis of porphobilinogen initially proposed by Shemin.
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