Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 345, Issue 1-2, Pages 195-201Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200390011
Keywords
asymmetric hydrogenation; DuPHOS; imine hydrogenation; ruthenium
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A range of aromatic and cyclic imines were subjected to asymmetric hydrogenation with catalysts derived from complexes of the type RuCl2(diphosphine)(diamine). Good to high enantioselectivities were observed. For each imine, a library of chiral complexes based on different diphosphine and diamine combinations was screened. A different combination of diphosphine and diamine was required each time to obtain the optimum enantioselectivity.
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