Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 345, Issue 1-2, Pages 169-171Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200390005
Keywords
asymmetric catalysis; diphosphinite; diphosphite; hydrogenation; imines; iridium; P-ligands
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Iridium complexes incorporating xylose diphosphinite 1 and diphosphite 2, 3 ligands as source of chirality are active catalysts for the hydrogenation of imines providing moderate ee. The enantioselectivity depends on the fine tuning of the structural parameters of the ligand and on the effect of additives.
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