Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 345, Issue 1-2, Pages 222-229Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200390016
Keywords
biphasic catalysis; colloids; counter-ions; hydrogenation; rhodium; surfactants
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A reduced aqueous colloidal suspension of rhodium shows an efficient activity in the catalytic hydrogenation of various benzene derivatives under biphasic conditions at room temperature and under atmospheric hydrogen pressure. The rhodium nanoparticles in the size range of 2 - 2.5 nm have been synthesised by reducing RhCl3 . 3 H2O with sodium borohydride and were stabilised by highly water-soluble N,N-dimethyl-N-cetyl-N-(2-hydroxyethyl)ammonium salts (HEA16X, X = Br, Cl, I, CH3SO3, BF4). The major influence of the counter-ion of these surfactants on catalytic activity and recycling is described. The best results have been obtained with chloride ammonium salts HEA16Cl.
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