Journal
REACTION KINETICS AND CATALYSIS LETTERS
Volume 81, Issue 1, Pages 169-175Publisher
SPRINGER
DOI: 10.1023/B:REAC.0000016531.63864.45
Keywords
saccharides; nickel; hydrogenation; polyols
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Kinetic evaluations were accomplished in a discontinuous three-phase reactor for saccharose, glucose and fructose hydrogenations at 373, 393 and 413 K, and 24 atm. Selectivities attained values in the order of 99.05%. Langmuir-Hinshelwood models based on heterogeneous mechanisms were proposed and the optimization and kinetic quantification of the process were performed.
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