Journal
EUROPEAN JOURNAL OF PHYSICS
Volume 25, Issue 1, Pages 15-22Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0143-0807/25/1/003
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Trouton's empirical rule for the entropy of vaporization is shown to follow from the similarity of the potential function of molecular interaction, hence is associated with the law of corresponding states. This fact explains the deviations from the rule for different groups of substances.
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