Journal
LETTERS IN ORGANIC CHEMISTRY
Volume 1, Issue 1, Pages 6-11Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570178043488590
Keywords
porphyrin; nanostructure; scanning probe microscopy; self-assembly; supramolecular chemistry; confocal fluorescence microscopy
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A novel cross-shaped porphyrin pentamer having four imidazolyl-porphyrinatozinc(II) moieties, one at each meso-position, was prepared. AFM measurements confirmed the formation of a large two-dimensional porphyrin array structure: a thin layer of 6-7 porphyrins was assembled over a 350 x 350nm(2) area, representing linkage of approximately 120 pentamer units along the line of the cross.
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