4.5 Article

Thermodynamic admissibility of the reptation model

Journal

JOURNAL OF RHEOLOGY
Volume 48, Issue 1, Pages 53-67

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JOURNAL OF RHEOLOGY AMER INST PHYSICS
DOI: 10.1122/1.1631424

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In a recent paper, Ottinger and Beris assert that the celebrated Doi-Edwards (DE) model for entangled polymer dynamics is incompatible with the so-called GENERIC form of nonequilibrium thermodynamics. Simply put, they claim that the DE model for tube dynamics is inconsistent with the principle of virtual work. I show that with the correct choice of effective Hamiltonian, namely the full tube configurational entropy, the DE stress tensor does in fact result from a virtual work argument. (C) 2004 The Society of Rheology.

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