Journal
CATALYSIS TODAY
Volume 151, Issue 1-2, Pages 131-136Publisher
ELSEVIER
DOI: 10.1016/j.cattod.2010.02.023
Keywords
Fluorine; Surfactant; Decomposition; Perfluorooctanoic acid; Alternative
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The persulfate (S2O82-)-induced decomposition of hydroperfluorocarboxylic acids (H-PFCAs), that is, HCnF2n COOH (n =4, 6, and 8), in hot water was investigated, and the results were compared with the results for perfluorocarboxylic acids (PFCAs). This is the first report on the use of hot water to decompose H-PFCAs, which are being developed as alternative surfactants to environmentally persistent and bioaccumulative PFCAs. Although H-PFCAs showed almost no decomposition in hot water at 80 C in the absence of S2O82-, the addition of S2O82- to the reaction solution led to efficient mineralization to F- ions, with F- yields [(moles of F-)/(moles of fluorine in initial H-PFCAs)] of 96.7-98.2% after 6h of treatment. The decomposition of H-PFCAs induced by S2O82- also proceeded even at 60 C, at which the initial decomposition rates were 7.1-12.7 times those for the corresponding PFCAs. The reaction mechanism can be explained by nucleophilic substitution by SO4 center dot- at the carbon atom attached to the omega-H atom of the H-PFCAs, followed by formation of perfluorodicarboxylic acids (HOOCCn-1F2n-2COOH), which react with SO4 center dot- to give shorter-chain perfluorodicarboxylic acids: this process eventually resulted in complete mineralization to F- ions. (C) 2010 Elsevier B.V. All rights reserved.
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