Journal
CATALYSIS SURVEYS FROM ASIA
Volume 18, Issue 4, Pages 101-127Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10563-014-9169-8
Keywords
Zeolitic imidazolate frameworks (ZIFs); ZIF-8; Synthesis; Functionalization; Heterogeneous catalysis; Adsorption
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Funding
- National Research Foundation of Korea (NRF) Grant - Korean Government (MEST) [2013005862]
- National Research Foundation of Korea [2013R1A2A2A05005862] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Zeolitic imidazolate frameworks (ZIFs) are comprised of transition metal ions (Zn, Co) and a range of imidazolate linkers in a tetrahedral coordination similar to that in crystalline aluminosilicate zeolites. The high surface area, tunable nanoporosity that can be subject to functionalization and the excellent thermal/chemical stability of ZIFs are attractive for heterogeneous catalysis and selective gas adsorption/separation. This review presents the current trends in synthesis, surface modification and catalytic reactions/adsorption of ZIF-based materials with particular emphasis on ZIF-8, which is the most widely studied structure among ZIFs.
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