4.5 Article

Microscope Analysis of Au-Pd/TiO2 Glycerol Oxidation Catalysts Prepared by Deposition-Precipitation Method

Journal

CATALYSIS LETTERS
Volume 144, Issue 12, Pages 2167-2175

Publisher

SPRINGER
DOI: 10.1007/s10562-014-1382-6

Keywords

Nanoparticle catalyst; Glycerol oxidation; High-resolution EDS analysis

Funding

  1. Japan Society for the Promotion of Science (JSPS) KAKENHI [25340130]
  2. International Research Group 'EC-SAW' (Environmental Catalysis for Sustaining Clean Air and Water)

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Gold-palladium bimetallic nanoparticle catalysts prepared by a deposition-precipitation method were effective for aerobic oxidation of glycerol to carboxylic acids. The role of palladium was to suppress C-C bond cleavage that is responsible for the formation of C2 by-product molecules. The nanoparticles were observed by microscope techniques, which further enabled characterizing the respective locations of Au and Pd within the particles.

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