Journal
CATALYSIS LETTERS
Volume 143, Issue 11, Pages 1226-1234Publisher
SPRINGER
DOI: 10.1007/s10562-013-1043-1
Keywords
Transesterification; Glycerol; Glycerol carbonate; Dimethyl carbonate; Solid base; KF/Al2O3
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Funding
- Admar Mutt Education Foundation (AMEF)
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Glycerol carbonate was synthesized by transesterification of glycerol with dimethyl carbonate using KF supported catalyst. KF was impregnated on various oxides and non-oxide supports like Al2O3, SiO2, ZnO, ZrO2, H-beta, and carbon to study the influence of the support on the catalytic performance. The preparation procedure of supported KF catalysts was modified to remove weakly adsorbed KF from the catalyst surface. The generation of basic sites by KF depends upon the extent of KF interaction with the support. KF/Al2O3 catalyst with optimized amount of 3.8 mmol KF, gave the highest activity with 95.8 % glycerol conversion and almost 100 % selectivity for glycerol carbonate. It was truly heterogeneous without any leaching of active sites and also showed good reusability. The catalyst exhibited better performance when compared to conventional solid base catalysts such as MgO, CaO and hydrotalcite.
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