4.5 Article

Green Photocatalysis with Oxygen Sensitive BODIPYs under Visible Light

Journal

CATALYSIS LETTERS
Volume 144, Issue 2, Pages 308-313

Publisher

SPRINGER
DOI: 10.1007/s10562-013-1122-3

Keywords

BODIPY; Photocatalysis; Green chemistry; Homogeneous catalysis

Funding

  1. National Natural Science Foundation of china [21104075]

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Four oxygen-sensitive meso-phenyl group with p-azo function Boron-dipyrromethene (BODIPY) dyes were synthesized, and their structures and photophysical properties were studied by H-1 NMR, cyclic voltammetry and emission spectroscopy. Oxygen-sensing properties of BODIPYs are relevant to their catalytic activity under visible light. They were used to photocatalize oxidation of thioanisole. These metal-free visible-light catalytic agents could complete 100 % conversation from thioanisole to methylphenyl sulfoxide.

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