Journal
CATALYSIS LETTERS
Volume 142, Issue 8, Pages 1003-1010Publisher
SPRINGER
DOI: 10.1007/s10562-012-0862-9
Keywords
Catalysis; Zinc; Deoxygenation; Sulfoxide; Sulfide
Categories
Funding
- Cluster of Excellence Unifying Concepts in Catalysis
- Deutsche Forschungsgemeinschaft
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In the present study, the zinc-catalyzed deoxygenation of aliphatic and aromatic sulfoxides in the presence of boranes as reducing reagent has been explored. After investigation of different reaction parameters the abilities of catalytic amounts of Zn(OTf)(2) has been demonstrated in the deoxygenation of various sulfoxides. Moreover, various experiments have been performed to shed light on the underlying reaction mechanism.
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