4.5 Article

Effects of Ligands, Cluster Size, and Charge State in Gas-Phase Catalysis: A Happy Marriage of Experimental and Computational Studies

Journal

CATALYSIS LETTERS
Volume 142, Issue 11, Pages 1265-1278

Publisher

SPRINGER
DOI: 10.1007/s10562-012-0892-3

Keywords

Bond activation; Catalysis; Transition metals; Reaction mechanisms; Elementary steps

Funding

  1. Fonds der Chemischen Industrie
  2. Deutsche Forschungsgemeinschaft within the Cluster of Excellence: Unifying Concepts in Catalysis

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We present selected examples of gas-phase reactions which are of timely interest for the activation of small molecules. Due to the very nature of the experiments, detailed insight in the active site of catalysts is provided and-in combination with computational chemistry-mechanistic aspects of as well as the elementary steps involved in the making and breaking of chemical bonds are revealed.

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