Journal
CATALYSIS LETTERS
Volume 143, Issue 1, Pages 122-125Publisher
SPRINGER
DOI: 10.1007/s10562-012-0943-9
Keywords
Oxidation and reduction reactions; Palladium acetate; Metal-organic framework; Selectivity
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Funding
- National Research Foundation of Korea
- Korean Government [2012-003212]
- Inha University
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A palladium containing metal-organic framework (MOF) compound has been synthesized from MOF, (Zn4O)(3)(BDC-NH2)(3)(BTB)(4) through Schiff base condensation reaction and complexation of Pd(II). Pd-MOF was found to be an effective heterogeneous catalyst for the oxidation and hydrogenation of various substrates under mild reaction conditions. This catalytic method is highly active and shape selective.
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