Journal
NATURAL PRODUCT REPORTS
Volume 21, Issue 5, Pages 575-593Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b315020h
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Modular polyketide synthases biosynthesise natural products through successive Claisen-type condensations, where one module is responsible for one round of chain extension. This review describes recent findings where this rule of co-linearity is broken, either by one module being bypassed ( skipping) or through one module being used for multiple chain extension events ( stuttering).
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