4.5 Article

Bronsted Acidic Ionic Liquids Mediated Metallic Salts Catalytic System for the Chemical Fixation of Carbon Dioxide to Form Cyclic Carbonates

Journal

CATALYSIS LETTERS
Volume 141, Issue 12, Pages 1838-1844

Publisher

SPRINGER
DOI: 10.1007/s10562-011-0682-3

Keywords

Bronsted acidic ionic liquids; Carbon dioxide; Epoxide; Cyclic carbonate

Funding

  1. Chinese National Sciences Foundation [21006021]
  2. Natural Science Foundation of Heilongjiang Province of China [ZD200820-02]
  3. Science & Technology Plan of Heilongjiang Province of China [GZ08A402]
  4. Science & Technology Reseach Foundation of Heilongjiang Province Education Bureau of China [11531266]

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The catalysts of COOH- and SO3H-functionalized ionic liquids mediated metallic salts had been developed for the coupling of carbon dioxide and epoxides to form cyclic carbonates under mild reaction conditions without using additional organic solvents. The effects of different ionic liquids, metallic salts, varying the molar ratio of ionic liquid to metallic salt and reaction conditions were examined. The excellent yield of cyclic carbonates and the high turnover frequencies (TOF) were obtained at the optimum reaction conditions. In addition, the catalytic system offered high stability and reusability.

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