Journal
CATALYSIS LETTERS
Volume 141, Issue 9, Pages 1288-1296Publisher
SPRINGER
DOI: 10.1007/s10562-011-0652-9
Keywords
Cyclohexanol dehydrogenation; FeTiMCM-41
Categories
Funding
- Bulgarian-Hungarian Inter-academic Exchange Agreement
- [DO02-295_2008]
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Iron and titanium modified MCM-41 materials, prepared by direct synthesis were investigated using X-ray diffraction (XRD), nitrogen physisorption, UV-Vis diffuse reflectance, Mossbauer, FT-IR and EPR spectroscopies. Materials with high surface area and well-ordered pore structure were obtained. All modified mesoporous silicas possess high activity in cyclohexanol conversion. FeTiMCM-41 (Si/Ti = 10, Si + Ti/Fe = 15) catalyst presented the highest activity and selectivity to cyclohexanone.
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