Journal
CATALYSIS LETTERS
Volume 141, Issue 5, Pages 705-708Publisher
SPRINGER
DOI: 10.1007/s10562-011-0563-9
Keywords
N-heterocyclic carbene; Rhodium complex; 1,4-Conjugate addition; Arylboronic acids; Water; Synthetic methods
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Funding
- National Natural Science Foundation of China [21002072, 20702013]
- Department of Education of Zhejiang Province [Y200907072]
- Wenzhou University
- Science and Technology Department of Zhejiang Province [2010R424050]
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N-Heterocyclic carbene-rhodium(I) complexes derived from N-benzyl substituted proline have been successfully synthesized and were found to be efficient catalysts for the 1,4-conjugate addition of arylboronic acids to enones in neat water at 40 A degrees C. Under the optimal reaction conditions, all reactions gave the addition products in good to high yields.
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