Journal
CATALYSIS LETTERS
Volume 139, Issue 1-2, Pages 38-41Publisher
SPRINGER
DOI: 10.1007/s10562-010-0394-0
Keywords
Cyclic carbonate; Carbon dioxide; Epoxide; Polyoxometalate
Categories
Funding
- Natural Science Fund Council of China [20731002, 20801004, 10876002, 20801005, 20973023]
- Beijing Education Commission [20091739006]
- Beijing Technology Commission [Z09010300820902]
- Specialized Research Fund for the Doctoral Program of Higher Education [200800070015]
- State Key Laboratory of Explosion Science and Technology
- Beijing Institute of Technology [ZDKT08-01, 1020020450802, YBKT09-13]
- Postgraduate innovative Research Foundation of Beijing Institute of Technology [AA200804]
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The tetra-n-heptylammonium salts of transition-metal-substituted (TMS) Keggin type germanotungstates [(n-C(7)H(15))(4)N](n)GeW(11)MO(39) (M = Mn(2+), Fe(3+), Co(2+), Ni(2+), Cu(2+) and Zn(2+), n = 5 or 6) were found to be efficient catalysts for cyclic carbonates synthesis from epoxides and CO(2) under solvent-free and halogen-free condition. The catalytic activities were significantly influenced by the transition metal and the countercation and a plausible mechanism was proposed.
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