Journal
CATALYSIS LETTERS
Volume 141, Issue 3, Pages 370-373Publisher
SPRINGER
DOI: 10.1007/s10562-010-0477-y
Keywords
Density functional theory; Stepped surfaces; Coupling reactions; Bond breaking reactions; BEP relations; Scaling relations
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Funding
- Lundbeck Foundation
- Danish Ministry of Science, Technology, and Innovation
- U.S. Dept. of Energy, Office of Basic Energy Sciences
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It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals.
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