Journal
CATALYSIS LETTERS
Volume 137, Issue 3-4, Pages 111-117Publisher
SPRINGER
DOI: 10.1007/s10562-010-0347-7
Keywords
Gallium triflate; Hydroamination; Organosilanes; Green chemistry; Organic synthetic transformations
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Funding
- Loker Hydrocarbon Research Institute
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Direct hydroamination of aldehydes and ketones provides one-step entry into desired alpha-aminoalkane derivatives which are important synthons for many biologically active molecules. The reductive amination of aldehydes in the presence of silanes has been effectively promoted by Ga(OTf)(3) as a catalyst. Mild conditions, easy work-up and high purity of products with excellent yields are the major advantages of this method.
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