4.5 Article

Oxidation of Glycerol with Oxygen in a Base-free Aqueous Solution over Pt/AC and Pt/MWNTs Catalysts

Journal

CATALYSIS LETTERS
Volume 130, Issue 1-2, Pages 185-191

Publisher

SPRINGER
DOI: 10.1007/s10562-009-9849-6

Keywords

Glycerol oxidation; Glyceric acid; Pt; MWNTs

Funding

  1. Zhejiang Provincial Natural Science Foundation [Z406142]
  2. National Natural Science Foundation of China [90610002]
  3. Ministry of Science and Technology of China [2007CB210207]

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Catalytic oxidation of glycerol with molecular oxygen to glyceric acid was performed in a base-free aqueous solution over Pt/MWNTs and Pt/AC catalysts. Pt/MWNTs was more active for the easier accessibility of Pt on the external wall of MWNTs, and the initial TOF reached 10.63 mmol min(-1)/mmol-Pt. The easier accessibility of glycerol to Pt particles on MWNTs was confirmed by Raman.

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