4.5 Article

Catalytic Conversion of Glucose on Al-Zr Mixed Oxides in Hot Compressed Water

Journal

CATALYSIS LETTERS
Volume 133, Issue 1-2, Pages 221-226

Publisher

SPRINGER
DOI: 10.1007/s10562-009-0160-3

Keywords

Solid solution; Glucose; Lactic acid; Mixed oxide; Hot compressed water

Funding

  1. SINOPEC Foundation [X505005]
  2. Scientific Research Foundation for the Returned Overseas Chinese Scholars of China

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A series of Al-Zr mixed oxides with different molar ratios was prepared by coprecipitation method and characterized by N-2 physiorption, XRD, NH3-TPD and CO2-TPD. Solid solution is formed in the mixed oxides. And the composition of the mixed oxides has significant influence on their acid-base properties. The catalysts were examined with glucose reaction in hot compressed water at 180 A degrees C. The prepared oxides exhibit very good catalytic activity and glucose conversion can be increased from 46.6 to 85%. The products distribution is related with the acid-base property of the oxide.

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