4.5 Article

Ru Nanoparticles Entrapped in Mesopolymers for Efficient Liquid-phase Hydrogenation of Unsaturated Compounds

Journal

CATALYSIS LETTERS
Volume 133, Issue 1-2, Pages 63-69

Publisher

SPRINGER
DOI: 10.1007/s10562-009-0130-9

Keywords

Periodic mesopolymer; Ru/FDU-15; Liquid-phase hydrogenation; Carbonyl compounds; Olefins

Funding

  1. NSFC [20703018]
  2. Shanghai Rising-star Project [08QA1402700]
  3. 973 Program [2006CB202508]
  4. Shanghai Leading Academic Discipline Project [B409]

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Ruthenium nanoparticles entrapped in periodic mesopolymers, Ru/FDU-15-H-2, were proved to be an effective and reusable catalyst for the liquid-phase hydrogenation of benzaldehydes, affording a constant activity after the 6th cycle in water. Besides the hydrogenation of benzaldehydes, Ru/FDU-15-H-2 catalyst can also catalyze the liquid-phase hydrogenation of arenes, olefins and other carbonyl compounds under mild conditions.

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