Journal
CATALYSIS LETTERS
Volume 125, Issue 3-4, Pages 197-200Publisher
SPRINGER
DOI: 10.1007/s10562-008-9533-2
Keywords
aryl chlorides; CC coupling; ligand free; palladium
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Palladium acetate has been shown to be a highly active catalyst for Heck reactions of aryl chlorides even in the absence of organic ligands. Bromobenzene can efficiently be coupled in presence of negligible traces of Pd, resulting in the highest TON (4.7 x 10(7)) and TOF (1.2 x 10(7) h(-1)) values that have ever been reported for this system up to now.
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