Journal
CATALYSIS LETTERS
Volume 126, Issue 3-4, Pages 213-217Publisher
SPRINGER
DOI: 10.1007/s10562-008-9688-x
Keywords
Oxidation; Benzyl alcohol; Au supported catalyst; Potassium titanates; Methyl benzoate
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Funding
- US National Science Foundation [CTS-0500471]
- PIRE [OISE-0730277]
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Gold nanoparticles are deposited on potassium titanate nanowires and used as heterogeneous catalysts in the aerobic oxidation of benzyl alcohol in methanol to methyl benzoate at ambient conditions. The presence of a catalytic amount of base promotes the reaction and the formation of free benzoic acid during the reaction poisons the catalyst. The activity however, of the catalyst can be restored again by addition of base.
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